Gulf coast location with midyear 1998 construction, total fixed cost increases in the order. Hydrocracking is an important unit as it is one of the three primary conversion processes available to the refiner along with fluid catalytic cracking fcc and coker. Uop offers various solutions for upgrading both atmospheric and vacuum residue streams. Since 2009, at least 15 unicracking twostage hydrocracking units have been. The resid hydrocracking process is becoming more and more important to refiners since it allows a higher conversion rate than other heavy oil conversion. Hydrocracking of heavy resid feedstock is forecasted to continue to grow over the coming decades, as large reserves of unconventional extraheavy crude are available in several regions around the globe. Bp plc starts resid hydrotreater unit train at texas city refinery. Comparison of thermal cracking and hydrocracking yield. Catalysts used for hydrocracking are bifunctional, as they comprise a hydrogenationdehydrogenation function provided by metals, and an acidic function given by the. Measuring density and level in resid hydrocrackers berthold. Processes for upgrading resid hydrocarbon feeds are disclosed.
Nan loots, a native and former resident of netherlands and wife of gary pitman coowner of refining community, will share her beautiful country with them, all while you arelearning about the best practices, protocols, and tech to maximize. Aug 07, 2014 more specifically, embodiments disclosed herein relate to solvent deasphalting of a residuum hydrocarbon feedstock, processing the resulting deasphalted oil in a residue desulfurization unit and a residue hydrocracking unit, and processing the pitch from the solvent deasphalting in a separate residue hydrocracking unit. Namely, boots on the ground approach to operations, engineering technical support, maintenance preventive, routine, and turnaround, inspection, and design engineering, procurement, and construction where we openly discuss issues and solutions that are common across the various licensors and unit configurations. The hoilrc rc stands for resid cracking process uses ebullatedbed hydrocracking technology to process heavy feedstock residues atmospheric and vacuum residue with high metals, sulfur, nitrogen, asphaltenes and solid contents. Resid hydrocracking is quickly emerging as todays hot refining technology to. Hydrocracking was first developed in germany as early as 1915 to provide liquid fuels derived from their domestic coal deposits. Getting the greatest value out of crude oil and effectively processing all the fractions from very light gas and naphtha to residue can be challenging. Case studies 114,894 bytes to highlight the advantages of two popular vacuum residue upgrading routes, coking and. The device can process a variety of heavy crude oil and ordinary crude oil residue, but the equipment investment is large. The developer of lyra residences is lyra residences limited partnership. It is a similar unit yielding a similar range and quality of products, but it is designed to handle heavier atmospheric resid as a feed. Ebr systems provide contaminant removal central to control of sediment formation and maximum desulfurization activity. The reaction products flowed together from the top of the reactor. Fresh feed is mixed with a heavy vacuum gas oil diluent.
The feed to fluid catalytic cracking unit fccu is the most important process variable. Pros and cons of operating a fcc at maximum capacity. The layout of a typical unit there is no one solution for all refineries. The following are some of the resid hydrotreating unit operations, practices and daily troubleshooting techniques shared by veteran refining professionals at recent conferences around the world.
Hydrocracking petroleum refinery equipment for sale. The combined feed enters surge drum v33, is pumped to feed heater h01 then mixed with highpressure recycled hydrogen gas, is preheated in h02 in mixers, then fed to the reactor v01 at about 750f and 2450 psig see figure 3. Resid hydrotreating, lcfining, isotreating, isocracking. The feed to resid hydrocracker is crude unit vacuum bottoms. Hydrocracking technology plays a major role in meeting the need for cleanerburning fuels, effective feedstocks for fcc and petrochemical operations, and high quality lubricating oils. While slurry phase hydrocracking has been reliably practiced for several decades, it has not enjoyed widespread acceptance as the technology of choice for resid upgrading.
It uses high pressure, high temperature, a catalyst and hydrogen to crack heavier feedstock into lighter, more valuable. Modular equipment group to reduce onsite construction and. These products can be monetized directly as fuels, or. Axens to supply hydrocracking technology to shenghong. Hydrocracking is an important source of diesel and jet. Hydrocracking is an extremely versatile process that can be utilized in many different ways, and one of the advantages of hydrocracking is its ability to break down highboiling aromatic stocks produced by catalytic cracking or coking. Hydrocracking increases the degree of saturation of the products which. Resid hydrotreater unit rhu heat exchanger failure.
It details the safe limits of the individual refinery equipment in terms of pressure and temperature including the operational safety of piping systems. Modular equipment group to reduce onsite construction and facilitate enhanced process automation and advanced control. One employee sustained a minor injury during the emergency unit. Hydrocrackers use hydrogen and a catalyst to break down heavy crude oil molecules into various distillates and gasoline. Uops uniflex mc process is a slurry hydrocracking process which achieves the highest conversion and produces the maximum naphtha and diesel yield compared to other residue conversion technologies. Ebr systems provide contaminant removal central to control of sediment formation and maximum desulfurization activity for transportation fuel specifications. Resid hydrocracking processes heavier feeds to maximize diesel production. There are two main chemical reactions that occur once the oil gets there. The resid hydrocracking unit is a singletrain, twostage plant. Journal of industrial and engineering chemistry volume 27, 25 july 2015, pages 1224. Depending upon market demand, any of the three dominant resid conversion processescoking, resid fluid catalytic cracking rfcc, or hydrocracking can be a profitable option for using refinery resids. Hydrocracking is a catalytic hydrogenation process in which high molecular weight feedstocks.
The process consists of causing feed to react with. For operating units, understanding the relationship between thermal cracking and hydrocracking kinetics provides insights into the operational changes that can be made to optimise unit performance. This moderate pressure hydrocracking requires a lower initial investment while providing refiners with the opportunity to economically revamp the unit for higher conversion, higher throughput, more difficult feeds andor more stringent product quality specifications at a later date. This in turn resulted in a reduction in equipment wall thickness, whereas. This process also has the flexibility to use nonstandard feeds, such as heavy coker gas oil hcgo and deasphalted oil dao. Conversion levels vary from 52 vol% to 66 vol% to meet the seasonal fueloil demand, while maintaining sulfur levels below 1 wt%.
Resid hydrocracking better than delayed coking in case studies. Actual maps, distances, dimensions, square footage, floor plans, finishings and the views from the. Resid hydrocracking better than delayed coking in case. Hydrocracking unit refinery plant petroleum refining. Aug 10, 2017 the feed to resid hydrocracker is crude unit vacuum bottoms. Process modelling and pilot plant trials are part of the toolbox used to pinpoint the best catalysts for individual hydrocrackers and also to develop the most effective unit operating strategy. Due to the continual supply of fresh catalyst, the residuum hydrocracking unit rhu produces a constant yield of highquality products. Jul 28, 2005 a facility experienced a major fire in its resid hydrotreater unit rhu that caused millions of dollars in property damage. Residue molecules are thermally cracked by application of heat at high pressure and with sufficient residence time.
Topsoe offers hydrotreating catalysts and technologies for all crude oil fractions, enabling refineries to meet product specifications at a low cost and with higher profits. In recent years, the cost for high pressure equipment has gone down very. Due to the continual supply of fresh catalyst, the resid hydrocracking unit. The rhdc processes are becoming more common worldwide and thus there is a need to share best practices around safety and reliability. The rcc resid catalytic cracker is a variant on the fcc. Residue conversion processes fixed, moving and ebulated beds use. The combined feed enters surge drum v33, is pumped to feed heater h01 then mixed with highpressure recycled hydrogen gas, is preheated in h02 in mixers, then fed to the reactor v01 at about 750f. The rcd unionfining process is a fixedbed catalytic hydrotreating process, combining unique process design parameters with stateoftheart residue hydrotreating catalysts. This brand new stateoftheart residue hydrocracking unit will allow shenghong to further improve their economic resilience and competitiveness while producing highly valuable petrochemical prone feeds. Axens will also supply hyk catalysts, equipment and full services offer from personnel training to plant startup. Resid hydrocracker produces lowsulfur diesel from difficult. We provide solutions for the integration of the hydrotreating unit with your downstream conversion unit. Although this process has been around for 50 years, it only recently. Scott sayles and sim romero, kbc advanced technologies.
The application of various technological advancements and core developments has been raising the bar in the design, build, operations and maintenance of h2 facilities. Design, equipment on some high pressure, heavy wall piping systems, the pipe is welded to the equipment nozzle, requiring the equipment to be tested with the piping system. Hydrocracking of residual oils mainly increases the production of high quality middle distillates for blending into jet and diesel fuels while reducing the volume of low value, high sulfur residual fuel oil. Resid hydrotreater unit rhu heat exchanger failure resid hydrotreater unit rhu heat exchanger failure. Process chemistry the uniflex process unit is a thermal cracking hydrogenation process. The mc catalyst system can also be supplied as part of an engineered, modular supply from uops. Though coking, resid fluidized catalytic cracking rfcc, and hydrocracking are the major commercial. Resid hydrocracking solutions ebullating bed resid ebr for bottoms cracking and upgrading uses dcs, ecad, ls, hsls, and hcrc series solutions. There are also annual programmes in progress for each of the following proprietary hydroprocessing technologies. Fcc is considered as gasoline making machine, although it also produces olefins, and delayed coking has been the primary technology of choice for converting vacuum resid to. The resid hydrocracker yields a high volume of kerosene and light gasoil distillate of good quality high cetane and low sulfur. There are currently 14ebullatedbed residue hydrocracking units in. Hydrocracking unit hydrocracking reactor fired heater hydrocracking cold seperator fractionator hydrocracking hot separator choose equipment hydrocracking is a process of catalytic cracking in the presence of hydrogen.
Residue hydrocracking rhc has gained traction as the desired residue conversion process in recent years. The choice of technologies depends upon both the quality of the resid stream and the quality of the final fuels products produced. Residue upgrading helps refiners get more from a barrel of oil and adds more to your bottom line. Hydrocracking units, also known as hydrocrackers, are types of process equipment used in petroleum refining. Chevron tests heavy oil hydrocracking technology oil.
For example, hightemperature fouling of heat exchangers and letdown valves are common across all types of rhdc units. A hydrocracking unit takes heavy gas oil from the atmospheric tower, the. Section 100 hydrocracking unit section 200product separation unit 1 section 300solvent deasphalting unit 1. The first process hydrocracks vacuum residue in ebullated bed reactors in a single stage without heavy oil recycle. Full conversion of resid provides higher yields refinery operations. Feb 08, 2019 resid hydrocracking is quickly emerging as todays hot technology. Aug 19, 2019 the resid hydrocracking reactions are conducted in an ebullated or fluidized bed reactor to overcome the problems associated with a fixed. Hydrocracking processes distillate hydrocracking is a refining process for conversion of heavy gas oils and heavy diesels or similar boilingrange heavy distillates into light distillates naphtha, kerosene, diesel, etc. Middle distillates can be blended into jet fuel and diesel fuel. The process of claim 4, wherein the hydrocracking reactor system.
Obtaining the maximum performance from existing residua upgrading equipment is achieved by maximum asset utilisation. A facility experienced a major fire in its resid hydrotreater unit rhu that caused millions of dollars in property damage. The image below is a schematic depiction of the equipment and the process flow streams in a typical refinery hds unit. The liquid feed at the bottom left in the diagram is pumped up to the required elevated pressure and is joined by a stream of hydrogen. The resid hydrocracker upgrades vacuum resid through cracking while.
The key process safety design features of onsite process equipment, such as furnaces, pumps, compressors and heat exchangers, are covered, as well as offsite facilities including atmospheric. A resid hydrocracker is a variant on the typical vgo hydrocracker. Library refinery experiences crude blending and desalting coking visbreaking resid fluid catalytic cracking resid hydrocracking resid hydrotreating. The process is currently in the research and development stage in china.
Our approach will be the same for rhdc as it has been for delayed coking dcu, fluid catalytic cracking. Case studies 114,894 bytes to highlight the advantages of two popular vacuum residue upgrading routes, coking and hydroprocessing, ifp north america inc. Hydrocracking is an important source of diesel and jet fuel. Pros and cons of operating a fcc at maximum capacity published on march 27, 2017 march 27, 2017 207 likes 30 comments paul orlowski cokingfcc resid hydrocracking sda follow. To take full advantage of hydrocracking, the process must be integrated in the refinery with other process units. The study compares delayed coking plus hydrotreating vs.
Refining news delayed coking, fluid catalytic cracking. The catalyst is suspended in the liquid phase for hydrocracking reaction. Slurryphase hydrocracking of heavy oil and model reactant. Cracking of petroleum hydrocarbons was originally done by thermal cracking, which has been almost.
It is widely used to convert the highboiling, highmolecular weight hydrocarbon fractions of petroleum crude oils into more valuable gasoline, olefinic gases, and other products. Refining community resid hydrocracking for bottom of the barrel. Fluid catalytic cracking fcc is one of the most important conversion processes used in petroleum refineries. We provide solutions for the integration of the hydrotreating unit with your downstream conversion unit, optimizing your profit potential. One employee sustained a minor injury during the emergency unit shutdown and there were no fatalities. Description of hydrocracking process hydroprocessing for. The modern petroleum refinery has a series of core process units that create clean gasoline and low sulfur diesel fuel. Hydrocracking is widely used in petroleum refining to convert heavy oil fractions which may include residues into lower molecular weight hydrocarbons through cc bond breaking. No matter which you use, the residue hydrocracker process and technology. Comparison of thermal cracking and hydrocracking yield distributions. Maximizing the value of the bottom of the barrel is not limited to coking but also includes hydrogen addition processes like residue hydrocracking rhdc. Fresh catalyst is continuously added and spent catalyst withdrawn to control the level. Resid hydrocracking is growing technology in oil refining.
Return on resid processes depends on product differentials. During low fueloil demand cycles, the refinery operates at a higher conversion mode and produces greater quan resid hydrocracker produces. This severe fouling limitation leads other resid hydrocracking technologies to reduce their per pass conversion or to resort to recycle with the addition of a large volume aromatic solvent stream in an attempt to keep these unconverted asphaltenes in solution. Advances in residue hydrocracking digital refining. The figure below shows a typical hydrotech hydrotreating layout, with a hot separator and a cold separator. Also, it yields some heavy product vgo and vac resid range that must be further processed fcc or coker or blended into fuel oil. This function gives higher asphaltene conversion and prevents oil instability when the converted oil is cooled in downstream equipment. Chevron tests heavy oil hydrocracking technology chevron corp. It is also useful for converting highsulfur materials into lowsulfur fuels, making them more useful. There are also a number of different hydrocracker process equipment configurations. Ensure the equipment can be tested at the piping system pressure and that there are adequate vents and drains on the equipment pay special attention to vertical.
Due to the continual supply of fresh catalyst, the resid hydrocracking unit rhu produces a constant yield of highquality products. Although this type of oil refining has been around since the 1960s, it has just started gaining popularity. Because of the complexity of the combinations, this report determines the economics for each process individually. The function of the catalyst in a residue hydrocracking unit is to facilitate hydrogen transfer into the asphaltenes. Diesel hydrotreating dht occurs in the hydrotreater unit and involves the removal of impurities like sulphur and nitrogen from diesel feed in the presence of a catalyst and hydrogen. One of the worlds leading technology partnerships, chevron lummus global clg, provides not just an overview of rhc and its merits for maximizing a refinerys profitability, but also its impact on a refinerys capability to produce. Fccu feed has the greatest impact on operating conditions, yield and. A hydrocracking unit, or hydrocracker, takes gas oil, which is heavier and has a higher boiling range than distillate fuel oil, and cracks the heavy molecules into distillate and gasoline in the presence of hydrogen and a catalyst. Innovative resid cracking catalyst debottlenecks fcc unit. Even with its strengths of high asphaltene conversion and distillate selectivity, the specific set. Your technology configuration will, of course, depend on the feed, product specifications, unit pressure, makeup gas purity and more. These solutions are built on over 40 years of experience and dedication to meeting customer needs through innovation.
It is a similar unit yielding a similar range and quality of products, but it is designed to handle heavier vacuum resid as a feed. The cracking process begins when heavy oils are sent from the fluidized catalytic cracking unit fccu, the coker unit, and atmospheric or vacuum distillation tower to the hydrocracker. The lcfining residue hydrocracking process has inherent flexibility to meet. Mynah technologies, chesterfield, mo abstract the paper presents a case study on development and implementation of the operator training system for a greenfield hydrocracker unit at a large north american refinery. The first oil refinery unit is crude oil desalting. Hydrocracking is an important source of diesel and jet fuel source. Schematic diagram of a typical hydrodesulfurization hds unit in a petroleum refinery. Heated feed is mixed with a heated catalyst and injected into a reactor, where the catalyst freely mixes with the feed as a fluid.
The first plant that might be considered as a commercial hydrocracking unit began operation in leuna, germany in 1927. Am1273 1 lcmax and other lcfining process enhancements to extend conversion and onstream factor mario baldassari and ujjal mukherjee, chevron lummus global steve sukjin jung, gs caltex corporation abstract recent process enhancements incorporated into our lcfining unit designs and operating experience gained from. The developer reserves the right to make changes to the building and landscape design, floor plans and in unit specifications, equipment and features without prior notice. In a refinery the hydrocracking process which occurs in the hydrocracker unit hcu is a type of hydro processing operation where heavy oil is cracked in the presence of a catalyst and hydrogen to give cleaner fuels. Resid hydrocracking is quickly emerging as todays hot technology. In this effort, chevron lummus global clg is involved in operating dozens of pilot plants and micro units.
351 1419 1060 521 1433 1035 1270 237 931 778 718 1375 1223 628 1632 409 223 819 1489 848 137 1055 1217 1164 1054 1552 1277 89 1511 338 571 952 1218 1378 567 836 1463 489 577 1436 897 329 611